Huang, et al (2025) Long-term Cd remediation mechanisms and potential risks in soil with biochar application under dry-wet cycling at different soil moisture levels. Agricultural Water Management. https://doi.org/10.1016/j.agwat.2024.109212

Biochar, a carbon-rich material derived from organic waste, has shown potential in remediating cadmium (Cd)-contaminated soils. A recent study evaluated the long-term effects of biochar under simulated dry-wet cycles at varying soil moisture levels, representing 30 years of environmental exposure.

The study revealed three phases in Cd adsorption by biochar: an initial rapid phase (0-5 years), a stable equilibrium phase (5-20 years), and a slight re-release phase (20-30 years). Higher soil moisture levels (close to saturation) enhanced Cd immobilization, while drier conditions limited its effectiveness. Over 30 years, biochar consistently reduced bioavailable and leachable Cd in the soil, minimizing risks to plants and water systems.

Biochar’s effectiveness stems from its complexation with Cd via mineral and non-mineral components. Initially, non-mineral components dominated adsorption, but minerals played a larger role over time. However, prolonged aging reduced the mineral component’s contribution, potentially reactivating some Cd.

The findings underscore the importance of maintaining adequate soil moisture to optimize biochar’s remediation capabilities. Effective irrigation practices can minimize Cd reactivation by reducing excessive dry-wet cycles.

While biochar proves effective for long-term Cd immobilization, late-stage risks of re-release highlight the need for integrated field studies. These would validate lab findings and inform sustainable strategies for managing heavy metal-contaminated soils in agriculture and beyond.


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