Zeng, et al (2024)
Removal of aqueous oxytetracycline using copper-loaded biochar-activated peroxodisulfate: Synergistic mechanism of adsorption and nonradical 1O2. Journal of Environmental Chemical Engineering. https://doi.org/10.1016/j.jece.2024.114302

Antibiotic contamination in wastewater from livestock farming is an environmental concern. This study explores the use of copper- and nitrogen-doped biochar (Cu-N/BC) to remove oxytetracycline (OTC) from contaminated water. The biochar acts as a catalyst to activate peroxodisulfate (PDS), a chemical known for its ability to break down pollutants, through a dual process of adsorption and nonradical degradation.

Cu-N/BC was shown to have a high affinity for OTC, adsorbing 36.2 mg/g of OTC in just 30 minutes, with 97.24% of OTC being removed in 90 minutes when combined with PDS. Key to the process is copper’s ability to undergo valence cycling, which enhances PDS activation, leading to the generation of singlet oxygen (¹O₂), a nonradical reactive oxygen species (ROS) that effectively degrades OTC.

The study also identified the specific sites on the biochar surface, such as low-valent copper and nitrogen, which facilitate the degradation process. Furthermore, Cu-N/BC performed well across a broad pH range, showing potential for practical wastewater treatment.

This research offers insights into using biochar as a low-cost, efficient, and eco-friendly material for removing antibiotics from wastewater, with important implications for improving water treatment technologies.


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