Li, Huang, et al (2024) Attempts to obtain clean biochar from hyperaccumulator through pyrolysis: Removal of heavy metals and transformation of phosphorus. Journal of Hazardous Materials. https://doi.org/10.1016/j.jhazmat.2024.133837

In the realm of environmental sustainability, the proper disposal of heavy metal-rich plants resulting from phytoremediation is a paramount concern. This study pioneers an innovative approach, utilizing pyrolysis to transform phytoremediation residue (PR) into heavy metals-free and phosphorus-rich biochar. The research delves into the impact of chlorinating agents, dosage, and pyrolysis residence time on heavy metal removal, phosphorus transformation, and biochar properties.

Polyvinyl chloride (PVC) emerges as a key player, successfully removing 94.58% of zinc from the biochar, showcasing the efficacy of co-pyrolysis with PR. The study underscores the crucial role of biochar alkalinity in heavy metal leaching, emphasizing the need for comprehensive methods to evaluate heavy metal risks.

The results demonstrate that as chlorine dosage and pyrolysis residence time increase, biochar not only reduces heavy metal concentrations significantly but also enhances phosphorus bioavailability. The study highlights the potential of converting heavy metal hyperaccumulator plants into a valuable resource, offering new avenues for the treatment of hazardous wastes.

The introduction contextualizes the significance of phytoremediation and the challenges posed by heavy metal-contaminated plants. It explores various methods of PR treatment and underscores the dominance of pyrolysis in reducing pollutants while generating high-value products.

The conclusion calls for a shift in focus from solidifying and distributing heavy metals to their removal, presenting a promising direction for the future of PR-derived biochar. This study pioneers a sustainable solution, paving the way for cleaner biochar production and addressing the environmental challenges associated with heavy metal-rich plant disposal.



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