Xiang, Wang, et al (2024) Enhancing Cd (Ⅱ) Immobilization with Thiol-Modified Low-temperature Pyrolysis Biochar: Efficiency, Mechanism, and Applications. Journal of Environmental Chemical Engineering. https://doi.org/10.1016/j.jece.2024.112387

A recent study introduces a thiol-modified lotus seedpod biochar, labeled as LBS550, demonstrating promising applications in addressing cadmium (Cd) pollution in water and sediments. The research investigates the impact of thiol modification on Cd adsorption performance under different pyrolysis temperatures, revealing that low-temperature pyrolysis biochar exhibits the highest affinity for Cd(II). The modified biochar, derived from the often-discarded lotus seedpod, effectively adsorbed Cd(II) up to 68 mg/g in aqueous solutions, reducing available Cd in sediments by 31.1% to 43.5%.

The study explores the physicochemical properties, adsorption kinetics, isotherms, and mechanisms of the thiol-modified biochar. Oxidation and thiolation processes were found to impact the biochar’s surface properties, enhancing hydrophilicity. Notably, thiol-modified biochar demonstrated a predominant immobilization of Cd (II) through chelation, showcasing its potential for in-situ remediation.

Cadmium contamination poses a significant threat to the environment and human health, making effective remediation methods crucial. While various approaches exist, the study emphasizes the versatility and efficacy of thiol-modified lotus seedpod biochar in adsorbing Cd (II), providing insights into a cost-efficient remediation technique. The findings suggest the biochar’s potential in addressing Cd pollution, highlighting its role in water and sediment treatment. This research contributes to ongoing efforts to combat environmental contamination, offering a sustainable solution rooted in biochar modification and repurposing of abundant agricultural waste.



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