Bashir, M.H., Farhan, M., Samreen, T. et al.Effectiveness of constructed wetland technology-treated industrial wastewater on the spinach (Spinacia oleracea) health risks and biochar efficiency. Environ Geochem Health46, 469 (2024). https://doi.org/10.1007/s10653-024-02254-2


In peri-urban areas, industrial wastewater is commonly used for irrigation, introducing harmful metals like cadmium, chromium, lead, and nickel into the soil. This contamination deteriorates food quality and poses health risks. Biochar, a carbon-rich material, has been shown to reduce the mobility and bioavailability of these heavy metals, making it a potential solution for remediating contaminated soils.

A two-month pot experiment tested the effectiveness of different biochar levels on spinach growth using both untreated and treated industrial wastewater. The treatments included control (tap water), untreated wastewater, treated wastewater, and combinations of wastewater with biochar at 0.5% and 1%. The results showed that using treated wastewater with 1% biochar led to the best plant growth, with increased plant height, shoot weight, chlorophyll content, and improved photosynthetic and transpiration rates.

Biochar’s porous structure, high pH, and diverse functional groups played a key role in immobilizing heavy metals in the soil. Health risk assessments based on the U.S. EPA guidelines indicated that while all treatments had a hazard index (HI) below 1, the 1% biochar treatment further reduced HI and total cancer risk (TCR) in both adults and children.

The study concluded that using industrial wastewater for irrigation poses toxicity risks, but biochar significantly mitigates heavy metal contamination in soil and spinach, reducing associated health risks.


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