Liu, et al (2024) Magnetized bentonite modified rice straw biochar: Qualitative and quantitative analysis of Cd(II) adsorption mechanism. Chemosphere. https://doi.org/10.1016/j.chemosphere.2024.142262

Industrialization has exacerbated cadmium (Cd) pollution, posing significant environmental and health risks. A recent study explores a novel solution: magnetized bentonite modified rice straw biochar (Fe3O4@B-Bc), designed for efficient Cd(II) adsorption.

Biochar, produced through rice straw pyrolysis, was combined with magnetized bentonite clay, activated with KOH, and subjected to further pyrolysis. This process yielded Fe3O4@B-Bc, which effectively addresses the challenge of separating bentonite or biochar from water. The composite demonstrated a maximum Cd(II) adsorption capacity of 241.52 mg/g, outperforming previous modifications of rice straw biochar.

Characterization revealed that Fe3O4@B-Bc’s surface is enriched with carbon, oxygen, and iron functional groups, enhancing its adsorption efficiency. Quantitative analysis indicated that cation exchange and physical adsorption contribute 65.87% of the total adsorption capacity.

This study highlights the composite’s potential as a low-cost, recyclable green adsorbent for treating cadmium-contaminated water. Fe3O4@B-Bc’s high adsorption capacity and ease of separation make it a promising candidate for environmental remediation, offering an innovative approach to managing heavy metal pollution.


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