Liu, et al (2024) Recovery of biochar particles laden with lead in saturated porous media by DC electric field. Chemosphere. https://doi.org/10.1016/j.chemosphere.2024.141890

The study of biochar particle and lead (Pb^2+) co-transport in soil has unveiled a significant advancement in environmental remediation techniques. Given the toxicity of lead and its potential risks upon entering soil ecosystems, the need for efficient recovery methods is imperative. Biochar, a carbon-rich product derived from biomass, is recognized for its capacity to adsorb pollutants like heavy metals. However, its application in soil can lead to unintended environmental exposure due to the migration of pollutants facilitated by biochar particles breaking down into smaller fragments.

This research focused on the electrokinetic remediation method, a promising approach for addressing heavy metal contamination in soil with minimal secondary pollution. The study’s objective was to examine how a direct current electric field impacts the movement of biochar particles and Pb^2+ within a simulated soil environment. The findings reveal that the electric field significantly enhances the mobility and recovery of Pb-laden biochar particles, with a notable recovery efficiency of up to 78.8% under optimal conditions. Moreover, the electric field was observed to detach about 18% of the adsorbed Pb from biochar in high ionic strength environments.

Through detailed analysis based on the Convection-Dispersion Equation (CDE) model and Derjaguin-Landau-Verwey-Overbeek (DLVO) theory, the study proposes a two-stage strategy for maximizing the recovery of both biochar particles and Pb. This involves leveraging the electric field to first enhance biochar transport and subsequently facilitate Pb detachment and recovery.

These insights offer a valuable foundation for developing biochar recovery techniques aimed at mitigating potential environmental risks associated with biochar application in contaminated sites. By optimizing the conditions for electrokinetic remediation, this approach presents a viable solution for soil decontamination efforts, highlighting the potential for widespread application in environmental management and restoration projects.



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