Concrete has long been recognized for its ability to absorb atmospheric CO2 through a process called carbonation, where CO2 reacts with cement hydrates to form calcium carbonate. While this offers potential for carbon sequestration, the process slows over time, limiting its overall effectiveness. A recent study explores a breakthrough solution: integrating porous biochar into concrete formulations to enhance carbonation kinetics and CO2 capture capacity.

Porous biochar, derived from the pyrolysis of seaweed, exhibits a unique structure with interconnected micropores, mesopores, and macropores, combined with a hydrophilic surface rich in oxygen groups. These features allow biochar to act as a reservoir for water and CO2, enabling deeper and faster carbonation in concrete. By retaining water, biochar promotes the development of capillary pores in the cement matrix, which are crucial for CO2 diffusion and the formation of calcium carbonate.

The study demonstrated that biochar-enriched concrete significantly outperforms traditional formulations in terms of CO2 uptake. Experimental results showed that biochar accelerates CO2 diffusion through the material by creating a more open and interconnected pore network. This increased porosity allows CO2 to penetrate deeper into the concrete and react more efficiently with the cement components. Additionally, biochar particles enhance the chemical environment for carbonation, forming dense layers of calcium carbonate at the interface between the biochar and cement matrix. These layers not only sequester CO2 but also improve the material’s structural integrity.

Numerical simulations further confirmed the role of biochar in improving CO2 diffusion. The simulations revealed that CO2 flow within biochar-enriched concrete is redirected toward the biochar particles, where it is adsorbed into the micropores. The CO2 then diffuses through the biochar’s macropores, enhancing its penetration into the cement matrix. This mechanism, combined with biochar’s high CO2 adsorption capacity, results in a substantial increase in carbonation efficiency.

Moreover, the study identified secondary carbonation mechanisms facilitated by biochar. The water-rich environment near the biochar particles allows for the dissolution and reprecipitation of calcium carbonate, further enhancing CO2 capture. This process resembles natural geological systems where carbonate weathering occurs, providing an additional pathway for CO2 sequestration within the concrete.

Incorporating biochar also addresses sustainability challenges in construction. Biochar production utilizes biomass waste, offering a negative carbon footprint when the CO2 absorbed during biomass growth exceeds emissions from its processing. By substituting a portion of traditional cement materials with biochar, the construction sector can significantly reduce its carbon emissions while enhancing the performance of concrete.

This innovation positions concrete as more than just a structural material—it becomes an active tool for climate change mitigation. By integrating biochar into concrete, the industry can transform its largest material by volume into a carbon sink, aligning with global efforts to reduce greenhouse gas emissions. As this technology develops, it could revolutionize sustainable construction, making cities part of the solution to environmental challenges.


SOURCE: Mesnage, et al (2025) Porous biochar for improving the CO2uptake capacities and kinetics of concrete. Cement and Concrete Composites.https://doi.org/10.1016/j.cemconcomp.2025.105932


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