Tan, et al (2024) Comparison between Chemical Modification of Biochar for Different Environmental Applications. Chemical Engineering Transactions. DOI: 10.3303/CET24114090


Biochar, a carbon-rich material derived from biomass, has gained attention for its environmental applications, such as pollutant removal, soil remediation, and wastewater treatment. While biochar’s inherent properties, like porosity and functional groups, offer some utility, chemical modifications can significantly enhance its performance.

Common modification methods include acid/base activation, nanomaterial impregnation, and magnetization. Acid treatments with reagents like nitric acid (HNO₃) and phosphoric acid (H₃PO₄) enhance biochar’s oxygen-containing functional groups, surface area, and porosity, making it effective for adsorbing pollutants. Conversely, base activations using sodium hydroxide (NaOH) or potassium hydroxide (KOH) can increase surface area and alkalinity, favoring the adsorption of negatively charged pollutants.

Nanomaterial impregnation introduces elements like magnesium oxide (MgO) or iron (Fe) into biochar’s structure, creating specific active sites for targeted pollutant removal. Magnetization, achieved using iron-based compounds, not only enhances pollutant adsorption but also facilitates easy recovery of biochar using magnets.

Despite these advancements, challenges like optimizing modification efficiency and reducing chemical waste remain. Future research could focus on scaling these methods for industrial applications and performing lifecycle assessments to ensure alignment with sustainability goals.

By tailoring biochar through these methods, its versatility and effectiveness in addressing environmental challenges can be greatly expanded.


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