Sun, et al (2024) Oxidative Hydrothermal Carbonization to Fabricate Versatile Magnetic Biochar for Fenton-Like Degradation of Phenolic Compounds. Journal of Environmental Chemical Engineering. https://doi.org/10.1016/j.jece.2024.114822

A recent study published in the Journal of Environmental Chemical Engineering explores an innovative method to tackle phenol pollution in water. Researchers developed a high-performance magnetic biochar (MBC) using oxidative hydrothermal carbonization of rice straw, facilitated by potassium ferrate. This process introduced multiple catalysis sites for activating hydrogen peroxide (H₂O₂), producing reactive oxygen species (ROSs) to degrade phenolic compounds effectively.

Phenols, widely used in industrial applications, are toxic and carcinogenic even at low concentrations, posing a significant environmental threat. Advanced oxidation processes (AOPs), particularly Fenton-like reactions, are prominent solutions for breaking down such pollutants. However, traditional Fenton systems often suffer from inefficiencies like iron residue generation. The newly developed MBC addresses these challenges with a synergistic iron-carbon matrix that accelerates the Fe³⁺/Fe²⁺ cycle, achieving 99.74% degradation efficiency for phenol concentrations of 75 mg/L.

Additionally, the biochar exhibited high recyclability, with only a slight drop in efficiency (to 87.95%) after five cycles. Its versatility extends to various phenolic derivatives and real water matrices, showcasing broad applicability.

The oxidative hydrothermal carbonization process not only enhances the graphitization and oxygen functionality of the biochar but also stabilizes iron species for sustained catalytic performance. This study underscores the potential of magnetic biochar as an environmentally friendly, efficient solution for pollutant degradation, marking significant progress in wastewater treatment technologies.


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