Garcia-Prats, González, & Sánchez (2024) Characterization of biochars of different origin and application to the anaerobic digestion of source-selected organic fraction of municipal solid waste under batch conditions and at different dosages. Frontiers in Chemical Engineering. https://doi.org/10.3389/fceng.2024.1384495


Anaerobic digestion (AD) is a widely used technology for treating organic waste and producing biogas, particularly methane, which is a renewable energy source. However, this process faces several challenges such as low methane yield and process instabilities. This study investigates the use of biochar (BC), a carbon-rich product derived from biomass, as an additive to improve AD performance when digesting the organic fraction of municipal solid waste (OFMSW).

Three different types of biochar (BC1, BC2, BC3) were produced and tested in varying doses (1%, 5%, and 10% w/w total solids) to evaluate their effects on methane production. These biochars were characterized using a suite of techniques, including scanning electron microscopy (SEM), gas chromatography (GC), and Fourier transform infrared spectroscopy (FTIR), among others. This characterization confirmed that the properties of biochar significantly depend on both the feedstock used and the production process.

The study findings revealed that BC3 notably increased methane production by up to 30% at a 5% addition rate, enhancing the overall efficiency of the AD process. In contrast, BC1 and BC2 decreased methane production at the lowest addition rate of 1%, highlighting the complexity of biochar’s effects on AD. A two-way ANOVA indicated that both the type and dose of biochar significantly influence methane yields, emphasizing that these factors cannot be considered independently.

Biochar not only aids in methane production but also improves the buffering capacity of the AD system against pH fluctuations and provides a surface for microbial biofilms, which are crucial for stable and efficient digestion. Furthermore, the study discussed the economic aspects of using biochar in AD, suggesting that while the initial costs are higher than traditional additives, the increase in biogas production could make this a viable option financially.

The incorporation of biochar into AD processes could potentially mitigate common operational challenges, enhance biogas quality, and increase methane yield, making it an attractive option for waste management strategies. This study underscores the importance of tailored biochar applications based on specific feedstock and operational conditions to optimize anaerobic digestion processes. Further research is needed to refine the application protocols and confirm the long-term benefits of biochar in AD systems.


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