Wu, et al (2024) Cellulose-based mugwort biochar constructs p-n heterojunction micro interfaces to regulate the photocatalytic oxidation of As(III) by ferromanganese ions. Separation and Purification Technology. https://doi.org/10.1016/j.seppur.2024.129867


A new study explores the potential of mugwort straw biochar to remove arsenic (As(III)) from water. Researchers used mugwort, an abundant agricultural waste, and modified it into a biochar catalyst to improve arsenic oxidation. The key innovation in this research is the construction of p-n heterojunctions by loading the biochar with manganese oxyhydroxide (MnOOH) and iron oxyhydroxide (α-FeOOH). These modifications increase the biochar’s ability to generate active sites for photocatalytic reactions.

By delignifying the mugwort straw, the researchers exposed more hydroxyl groups, enhancing metal ion stability on the biochar’s surface. This treatment also increased the biochar’s porosity, further boosting its effectiveness in arsenic removal. Additionally, high-energy electron beam irradiation was used to enhance the photocatalytic properties of the modified biochar. The results showed that treated biochar could oxidize arsenic up to 12.31 times more efficiently than untreated biochar.

The study demonstrates how p-n heterojunctions facilitate the separation of charge carriers, enhancing the overall photocatalytic performance. This innovation offers an eco-friendly, low-cost solution for arsenic pollution in water. It also highlights the broader potential of using waste biomass like mugwort straw to develop sustainable environmental technologies.

The findings contribute valuable insights into biochar’s potential for water remediation, emphasizing its role in addressing heavy metal contamination in aquatic systems.


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