Wei, et al (2024) Study on the Adsorption Performance of Biochar/Montmorillonite Composites for Ciprofloxacin Hydrochloride. Journal of Physics: Conference Series. https://doi.org/10.1088/1742-6596/2920/1/012010


Antibiotic pollution in water, particularly from ciprofloxacin hydrochloride (CIP), poses significant environmental and health risks. A recent study explored the use of biochar/montmorillonite composites as efficient, low-cost adsorbents for removing CIP from wastewater.

The composites were prepared using pyrolysis and intercalation techniques. Compared to single materials, they offered improved surface areas and pore structures, enhancing their adsorption capabilities. Optimal ratios of montmorillonite to biochar were identified as 1.5:1 for pyrolysis and 2:1 for intercalation, resulting in superior CIP removal rates of 69% and 92%, respectively.

Key findings showed that these composites performed best in alkaline environments (pH 10), with adsorption efficiency influenced by temperature, CIP concentration, and contact time. Adsorption adhered to the Langmuir isotherm model, suggesting a uniform adsorption process. Thermodynamic studies revealed that the process was spontaneous, heat-absorbing, and accompanied by increased system disorder, promoting stability.

However, challenges remain. Recycling tests indicated a significant decline in adsorption capacity after five cycles, highlighting the need for improved regeneration methods. Despite these limitations, the study demonstrates the potential of biochar/montmorillonite composites as sustainable solutions for antibiotic wastewater treatment, leveraging agricultural byproducts like rice husks.

Future research should expand on other pollutants and optimize composite regeneration methods to enhance long-term efficiency. This study marks a promising step toward addressing the pressing issue of antibiotic pollution in water bodies.


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