Chen, et al (2024) A universal synthesis strategy for facile and scalable of magnetic biochar composite materials for PMS activation: catalytic mechanisms. Journal of Alloys and Compounds. https://doi.org/10.1016/j.jallcom.2024.174313


In recent advancements, researchers have developed a green and versatile pyrolysis strategy for synthesizing magnetic biochar composites as catalysts for Advanced Oxidation Processes (AOPs), aimed at enhancing wastewater treatment technologies. This innovative approach, characterized by its non-selectivity towards biomass species, leverages iron (Fe) nanoparticles as activation centers to promote the formation of nitrogen-doped carbon nanotubes (CNTs) during the annealing process. The pivotal role of surface-bound free radicals in this method underscores its efficacy, particularly in the rapid removal of sulfadiazine (SDZ), achieving over 90% efficiency within just 20 minutes across various biomass sources including duckweed, shrimp shell, peanut shell, corncob, and pomelo peel.The encapsulation of Fe nanoparticles within the nitrogen-doped CNTs, facilitated by the decomposition of melamine and biomass, not only circumvents the limitation of specific biomass requirements but also enhances catalytic performance through the formation of a specialized structure. This structure is further optimized by the migration of graphene sheets and carbon nanoparticles to the nucleus surface, resulting in a hollow CNT configuration.Furthermore, experimental findings, through quenching experiments and Electron Spin Resonance (ESR) tests, have elucidated the accumulation of surface-bound radicals on the CNTs surface, significantly contributing to the efficient SDZ removal. This synthesis strategy introduces a universal method for creating biochar-based catalysts, highlighting the relationship between biomass feedstock and catalytic properties, and offering a new pathway for environmental remediation through the utilization of waste resources. The approach not only simplifies the preparation process of biochar-based catalysts but also addresses performance variability, thereby presenting a significant step forward in the application of AOPs for pollutant degradation.



Leave a Reply

Trending

Discover more from Biochar Today

Subscribe now to keep reading and get access to the full archive.

Continue reading