Martínez-Toledo et al., in their study published in Materials Today Sustainability, explored the potential of using biochar derived from European hazelnut shells as a sustainable modifier for asphalt binder. The researchers investigated the impact of slow pyrolysis conditions, specifically temperature and residence time, on the physicochemical and antioxidant properties of the biochar. Their findings suggest that biochar obtained from hazelnut shells has the potential to enhance the performance and sustainability of asphalt roads.  

The excessive use of asphalt pavements has led to significant deterioration due to heavy traffic and harsh environmental conditions, particularly rising temperatures associated with climate change. Modifying asphalt binder with bio-additives derived from agricultural waste has gained attention as a sustainable solution. Hazelnut shells, a significant by-product of the hazelnut industry, have shown promise as a source of biochar due to their high lignin content and antioxidant properties.  

The study employed a factorial design with varying pyrolysis temperatures and residence times to produce biochar. They found that pyrolysis conditions significantly influenced the chemical composition and microstructure of the biochar. Higher temperatures and longer residence times resulted in increased carbon content and enhanced porosity. The biochar also exhibited antioxidant capacity, retaining a significant portion of the antioxidant properties present in the hazelnut shells.  

Confocal laser microscopy revealed a uniform distribution of biochar in the asphalt binder, indicating good compatibility between the two materials. Chemical interactions between the biochar and the binder were observed through FT-IR and XPS analyses, particularly in samples pyrolyzed at 300°C and 550°C for 1 hour. These findings suggest that biochar from hazelnut shells can effectively modify asphalt binder, potentially leading to improved performance and durability of asphalt pavements.  This research contributes to the growing body of knowledge on sustainable materials for road construction. By utilizing waste from the hazelnut industry, this approach promotes a circular economy and reduces the environmental impact of asphalt production. The use of biochar as a modifier for asphalt binder offers a promising pathway towards more sustainable and resilient road infrastructure.  


Source: Martínez-Toledo, C., Valdés-Vidal, G., Calabi-Floody, A., González, M. E., Ruiz, A., Mignolet-Garrido, C., & Norambuena-Contreras, J. (2025). Optimising Slow Pyrolysis Parameters to Enhance Biochar European Hazelnut Shell as a Biobased Asphalt Modifier. Materials Today Sustainability. https://doi.org/10.1016/j.mtsust.2025.101087


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