In a recent study published in Scientific Reports, Gitipour et al., explored using magnetic biochar to tackle this problem. They created this material by pyrolyzing siderite (an iron carbonate mineral) and sawdust in nitrogen gas. The resulting magnetic biochar has some interesting properties.  

The process of pyrolyzing siderite changes its chemical composition, turning it into a mix of hematite, magnetite, and maghemite. This change makes the biochar magnetic and also improves its surface.  The researchers tested the magnetic biochar’s ability to remove lead from water. They conducted adsorption experiments under different conditions, varying pH and temperature. To separate the biochar after it had adsorbed the lead, they used a magnet. An external magnet was used to easily separate the magnetic biochar suspension. The lead concentration was measured using a technique called Inductively Coupled Plasma (ICP) at Iran’s Geological Survey.  

The results were promising. The magnetic biochar showed a strong ability to adsorb lead ions. The highest adsorption capacity (96.92%) was observed at pH 5.0 and a temperature of 45°C. The biochar has a mesoporous structure. Adsorption was found to match Langmuir’s model, indicating that the lead ions form a single layer on the biochar’s surface. The adsorption process is quick, likely due to biochar’s active sites. The kinetics of lead adsorption aligned with a pseudo-second-order model, suggesting that chemisorption or surface complexation is the main mechanism.  

Importantly, the magnetic biochar can both adsorb lead and reduce it into less harmful forms. Plus, it can be easily recovered and reused because of its magnetic properties. The adsorption-desorption process was carried out five times, showing the magnetic biochar’s reusability. This makes it a potentially valuable tool for cleaning up lead-contaminated environments.  


Source: Gitipour, S., Sanaei, M., Lak, R., & Karbassi, A. (2025). Effective elimination of Pb (II) cations from waste water and polluted water using siderite magnetic biochar. Scientific Reports, 15(1), 7912.https://doi.org/10.1038/s41598-025-92073-x


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