Boron contamination in water is a pressing environmental and health issue, often stemming from industrial activities, geothermal processes, and desalination. Excess boron can harm aquatic ecosystems and human health, making its removal from water critical. Traditional removal methods, such as ion exchange and membrane distillation, face challenges like high cost and inefficiency. A recent study offers an innovative solution: functionalized biochar composites synthesized from date palm fibers, a renewable and sustainable feedstock.

The research developed five biochar composites—BC (carboxylated biochar), BC-PDA (polydopamine-loaded biochar), MBC-PDA (magnetic polydopamine biochar), BC-AlOOH (aluminum hydroxide biochar), and BC-ZnCl2 (zinc chloride biochar). These composites were designed to optimize boron adsorption through hydroxy-functional groups and high surface porosity. Their production involved simple and cost-effective methods, enhancing their viability for large-scale applications.

Adsorption experiments revealed that BC-AlOOH and BC-ZnCl2 exhibited the highest boron adsorption capacities of 43.2 mg/g and 44.2 mg/g, respectively, achieved within 120 minutes. The study found that adsorption efficiency peaked at a pH range of 8–9, aligning with the chemistry of boron species in water. The process was governed by pseudo-first-order kinetics, indicating a dominant chemical adsorption mechanism facilitated by hydroxy groups on the biochar surface.

These biochars demonstrated excellent reusability, retaining significant adsorption capacity across multiple cycles. This recyclability, combined with their high efficiency, positions them as sustainable alternatives to conventional adsorbents. Compared to other materials like activated carbon, the biochar composites showed superior performance, highlighting their potential for real-world applications.

This research underscores the promise of biochar as a low-cost, renewable solution to address boron contamination, paving the way for more sustainable water treatment technologies.


SOURCE: Amirshekari, et al (2025) Development of functionalized biochar composites for enhanced boron adsorption from aqueous solutions. Cell. https://doi.org/10.1016/j.heliyon.2025.e41720


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