Masuku, et al (2025) The development of multifunctional biochar with NiFe2O4 for the adsorption of Cd (II) from water systems: The kinetics, thermodynamics, and regeneration. Journal of Environmental Management. https://doi.org/10.1016/j.jenvman.2024.123705


The growing contamination of water sources by cadmium—a toxic heavy metal—poses significant environmental and health risks. Researchers from the University of South Africa have developed a promising solution: a zinc-doped nickel ferrite-pinecone biochar composite (ZNiF@PB). This innovative material effectively adsorbs cadmium (Cd(II)) ions from wastewater, offering a sustainable approach to water treatment.

The ZNiF@PB composite is produced by combining biochar, derived from pinecone biomass, with zinc-doped nickel ferrite nanoparticles. The material demonstrates an impressive cadmium removal efficiency of up to 96% under optimal conditions, which include a pH of 6, a 0.5g dose in 50 mL of water, and a contact time of 80 minutes. Its high surface area and abundant active sites enable strong cadmium adsorption, as confirmed by advanced analytical techniques like FTIR and XRD.

The adsorption follows a monolayer process best described by the Langmuir isotherm model, indicating that cadmium binds chemically to the composite’s surface. The material can be regenerated and reused for up to five cycles with minimal performance loss, making it cost-effective and practical for industrial applications.

ZNiF@PB also exhibits environmental advantages, such as minimal leaching of its components, ensuring safe water treatment without secondary pollution. This study underscores the potential of biochar composites in addressing heavy metal contamination and highlights opportunities for broader applications, including the removal of other pollutants like lead and arsenic.

ZNiF@PB is an eco-friendly and efficient solution to water contamination challenges, with strong prospects for scalability in wastewater treatment systems.


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