Minaei, et al (2024) Adsorption of sulfamethoxazole and lincomycin from single and binary aqueous systems using acid-modified biochar from activated sludge biomass. Journal of Environmental Management. https://doi.org/10.1016/j.jenvman.2024.120742

In recent advancements, the utilization of H3PO4-modified biochar, created through microwave pyrolysis from activated sludge biomass, has been studied for its potential to remove pharmaceuticals such as sulfamethoxazole (SMX) and lincomycin (LIN) from water systems. This approach not only aims to tackle the persistent issue of pharmaceutical residues in aquatic environments but also promotes the re-use of waste materials in an eco-friendly manner.

The study outlined the optimization of pyrolysis conditions to create a biochar with a significant surface area of 365 m²/g and enhanced porosity, which are crucial for effective adsorption. The biochar showed a greater affinity for adsorbing SMX over LIN, with maximum capacities of 45.6 mg/g and 26.6 mg/g, respectively. These findings underscore the role of hydrogen bonding and π-π interactions as the primary mechanisms for this adsorption process.

Further experiments evaluated the dynamic adsorption capacity of this biochar in both single and binary systems of the antibiotics, demonstrating its effectiveness in continuous-flow scenarios and not just in batch tests. This continuous system utilized biochar-embedded hydrogel beads and proved capable of significantly reducing antibiotic concentrations from real wastewater samples.

The synthesis process itself involves strategic microwave heating which promotes rapid, uniform temperature distribution, essential for activating the phosphoric acid-modified sludge biomass. This modified biochar thus not only benefits environmental sustainability efforts but also provides a cost-effective alternative to traditional activated carbon adsorbents.

These promising results serve as a foundational study for future research aimed at refining the use of sludge-based biochar in water purification technologies. This research highlights the potential of modified biochars to significantly impact environmental preservation and public health protection by efficiently removing harmful antibiotics from water systems.



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