He, Wang, et al (2024) Properties of biochar colloids and behaviors in the soil environment: Influencing the migration of heavy metals. Environmental Research. https://doi.org/10.1016/j.envres.2024.118340


In the realm of soil remediation, biochar emerges as a promising candidate for tackling heavy metal (HM) contamination. Derived through biomass pyrolysis, biochar undergoes processes that lead to the formation of micro- and nano-sized biochar colloids (BCs). These BCs, possessing rough surfaces, abundant elemental species, and multiple functional groups, exhibit unique colloidal properties due to their microscopic scale.

The migration of BCs in soil is a complex interplay influenced by colloidal properties and environmental factors such as soil colloids and conditions. The large specific surface area, rich oxygen-containing functional groups, and minerals on the BCs’ surface contribute to their mobility. Moreover, BCs may impact HMs in soil through various mechanisms, including electrostatic adsorption, ion exchange, surface complexation, and precipitation.

This comprehensive review sheds light on the physicochemical and migratory properties of BCs, emphasizing the internal and external factors shaping their movement in soil. The potential effects of BCs on HMs are highlighted, offering a theoretical foundation for optimizing HM-contaminated soil post-remediation using biochar. It also raises the need for targeted detection and analysis methods in future studies to confirm the innovative idea that BCs influence the presence of HMs in soil and mitigate potential environmental toxicities.



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