Sygula, et al (2024) The significance of structural components of lignocellulosic biomass on volatile organic compounds presence on biochar – a review. Wood Science and Technology. https://doi.org/10.1007/s00226-024-01557-y


Biochar, produced through the thermochemical processing of lignocellulosic biomass, has diverse applications in agriculture, construction, and environmental protection. However, the process of creating biochar, specifically through pyrolysis and torrefaction, releases volatile organic compounds (VOCs), some of which are harmful to the environment and human health.

Research indicates that during the conversion of biomass, VOCs can redeposit on the surface of biochar, posing potential hazards. Despite the extensive study of biochar’s benefits, there has been a lack of comprehensive analysis on the influence of biomass properties and processing conditions on VOC formation and redeposition.

A recent analysis identified ten VOCs from cellulose, hemicellulose, and lignin pyrolysis as harmful due to properties like carcinogenicity, toxicity, and mutagenicity. Among 140 identified compounds on biochar samples, 33 had harmful properties, indicating a significant risk of environmental contamination from compounds such as ketones, aldehydes, and polyaromatic hydrocarbons.

Biochar’s potential for energy production, soil remediation, and carbon sequestration is well-documented. However, the negative aspects, including the presence of harmful substances like PAHs, VOCs, and dioxins, need to be addressed. The release of these pollutants depends on process parameters and feedstock properties, necessitating systematic research to understand and mitigate these risks.

Ensuring the safe production and use of biochar requires recognizing and managing these hazards. As biochar continues to be a valuable resource, understanding the mechanisms of VOC formation and their environmental impact is crucial for sustainable biochar development. This calls for detailed studies on the interplay between feedstock properties, processing conditions, and VOC emissions to minimize potential environmental threats.


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