Zhao, Li, et al (2024) Unlocking the potential of Chinese herbal medicine residue-derived biochar as an efficient adsorbent for high-performance tetracycline removal. Environmental Research. https://doi.org/10.1016/j.envres.2024.118425


In a groundbreaking study, researchers harnessed the power of hydrothermal carbonization (HTC) along with ZnCl2 activation and pyrolysis to convert leftover astragali radix (AR), a traditional Chinese medicine residue, into a powerful biochar. This biochar, named HAR@ZnCl2, proved to be a sustainable and effective adsorbent for removing the antibiotic tetracycline (TC) from water.

Through a meticulous evaluation process involving adsorption isotherms, kinetics, and thermodynamics, the AR biochar showcased exceptional properties in TC removal. The biochar’s success was attributed to mechanisms such as pore diffusion, π-π interaction, electrostatic attraction, and hydrogen bonding. Impressively, HAR@ZnCl2 demonstrated a maximum adsorption capacity of 930.3 mg g−1 under specific conditions.

Not only did the biochar exhibit outstanding TC removal efficiency, but it also proved economically viable, with a payback of $701 per ton. Remarkably, even after ten cycles, HAR@ZnCl2 maintained a TC removal efficiency above 77%, highlighting its potential for long-term application in wastewater treatment.

This study underscores the transformative potential of AR biochar, derived from Chinese medicine waste, as a sustainable solution for purifying water contaminated with antibiotics.



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