Li, Liu, et al (2024) Mechanism of biochar composite (BN3Z0.5BC) activated peracetic acid for efficient antibiotic degradation: Synergistic effect between free radicals and non-free radicals. Bioresource Technology. https://doi.org/10.1016/j.biortech.2024.130452

In the pursuit of eco-friendly and efficient methods for antibiotics removal from water environments, a recent study introduces a promising solution. The research focuses on utilizing corn straw to synthesize biochar (BC) loaded with cobalt-zeolitic imidazolate framework nanoparticles and boron nitride quantum dots, resulting in the creation of BN3Z0.5BC. This composite efficiently activates peracetic acid (PAA), achieving an impressive 94.8% degradation of sulfadiazine (SDZ) in just five minutes, a five-fold increase compared to pure BC.

The mechanism analysis reveals a synergistic degradation pathway involving both free and non-free radicals. The defect structures on the BC surface act as active sites, stimulating PAA to produce more active species. Nitrogen-oxygen vacancies enhance charge transfer, contributing to the overall effectiveness of SDZ removal. The unique structure of BC ensures stability and recyclability while controlling metal leaching, addressing key challenges faced by traditional advanced oxidation processes.

The study addresses the growing concern of antibiotic pollution, particularly focusing on sulfadiazine released into the environment through livestock metabolites. It highlights the limitations of existing removal methods such as ozonation, photocatalysis, and electrocatalysis, paving the way for a novel approach utilizing PAA activated by BN3Z0.5BC.

By introducing low-cost and renewable biomass waste into the synthesis process, the study aligns with sustainability goals. The incorporation of cobalt-zeolitic imidazolate framework nanoparticles and boron nitride quantum dots enhances catalytic performance and stability, showcasing the potential for practical application across various water matrices.

In conclusion, this research presents a promising step towards environmentally friendly and efficient methods for antibiotic removal, emphasizing the significance of sustainable catalysts derived from biomass waste.



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