Li, et al (2024) Synergistic treatment of sewage sludge and food waste digestate residues for efficient energy recovery and biochar preparation by hydrothermal pretreatment, anaerobic digestion, and pyrolysis. Applied Energy. https://doi.org/10.1016/j.apenergy.2024.123203


Recent studies highlight a novel approach to managing sewage sludge (SS) and food waste digestate residues (DR) that improves dewaterability, mitigates heavy metal risks, and enhances energy recovery. This research explores the combined use of hydrothermal pretreatment (HP), anaerobic digestion (AD), and pyrolysis as a comprehensive waste treatment strategy.

Hydrothermal pretreatment (HP) effectively breaks down extracellular polymeric substances in SS and DR, significantly enhancing the dewaterability of these wastes. This pretreatment was conducted at 180°C, integrating 25% to 50% DR by mass which improved the solid content of the centrifuged cakes. Following HP, the liquid fraction exhibited high chemical oxygen demand (COD) and was processed through AD at 37°C. This stage produced substantial amounts of methane (CH4), ranging from 193.75 to 210.39 mL/g COD_input, which could potentially supply almost 90% of the HP energy requirements, significantly reducing energy inputs.

The AD process not only aids in energy recovery but also stabilizes the organic contaminants, shifting the microbial community from hydrogen to acetic acid utilization. This shift is crucial for enhancing methane production under varying DR ratios.

Subsequent pyrolysis of the HP and AD-treated materials at 700°C facilitated the production of biochar, which effectively immobilized heavy metals such as Zn, Cu, Ni, and Pb. The treatment ensured that these metals were locked in stable forms within the biochar structure, reducing ecological risks and leaching potential. The final biochar exhibited over 85% of these metals in residual fractions, posing a low ecological threat.

This integrated treatment method not only promises significant improvements in waste management by enhancing dewaterability and reducing heavy metal risks but also offers a sustainable way to recover energy and prepare valuable biochar. The approach demonstrates a viable alternative to conventional incineration and landfill methods, aligning with global efforts to reduce carbon emissions and advance circular economy practices in waste management. This innovative method leverages the synergistic potentials of HP, AD, and pyrolysis, setting a new standard for environmental sustainability in waste treatment technologies.



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