Miedzianowska-Masłowska, et al (2024) Waste management of straw to manufacture biochar: An alternative reinforcing filler for natural rubber biocomposites. Industrial Crops and Products. https://doi.org/10.1016/j.indcrop.2024.119629


This study investigates the potential of utilizing oat straw-derived biochar as a sustainable alternative to carbon black in natural rubber biocomposites. Carbon black, commonly used in rubber products like tires, has a high carbon footprint due to its fossil fuel origins. As the world aims for climate neutrality, biochar, produced through pyrolysis of agro-industrial residues, presents a renewable and eco-friendly alternative.

The research examined the effects of biochar produced at different pyrolysis temperatures (600°C and 900°C) on the mechanical and thermal properties of rubber composites. The findings revealed that biochar at 600°C was as effective as that at higher temperatures. Biochar-filled composites exhibited enhanced tensile strength compared to those filled with carbon black, reaching 21.3 MPa. However, these composites showed poor resistance to thermo-oxidative aging, which limits their durability.

Key tests, including rheometry and differential scanning calorimetry, confirmed that biochar can positively influence cross-linking in rubber. Despite its environmental benefits and mechanical strength, the susceptibility of biochar to aging requires further improvement. Strategies such as surface modifications or anti-aging additives could help enhance its performance.

The study suggests that biochar, as a renewable resource, could reduce dependency on fossil fuels in rubber production. However, its industrial application requires additional research, particularly to improve aging resistance for long-term use.


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