In a recent study published in Scientific Reports, a team of researchers including Syeda Minnat Chistie, Sneha Ullhas Naik, Pragathi Rajendra, Apeksha, Ranjeet Kumar Mishra, Gadah Albasher, Sampath Chinnam, Gautham P. Jeppu, Zeenat Arif, and Javaria Hameed, explored a promising method for tackling water pollution caused by textile industries. Their work focuses on producing and characterizing magnetic biochar from waste areca nut husk (ANH) to effectively remove methylene blue (MB) dye from wastewater.

Textile industries are significant contributors to water pollution due to their discharge of untreated colored effluents, which negatively impact the environment. Methylene blue, a common cationic dye used in various industries, poses substantial health risks to humans and aquatic life even in small concentrations. Traditional water treatment methods often come with high costs and challenges in managing secondary sludge. This has led researchers to investigate more sustainable and economical solutions like biochar.

Biochar has gained attention for its environmental remediation potential due to its simple design, ease of operation, large surface area, and cost-effectiveness. The current study specifically looked into slow pyrolysis of ANH to create magnetic biochar, a novel approach for dye removal. The researchers produced biochar at two different temperatures, 600 °C and 800 °C. The biochar produced at 800 °C (ANHB800) exhibited superior characteristics, including increased carbon content (62.93%), a higher heating value (33.02 MJ/kg), and a larger BET surface area (112 m²/g) compared to the 600 °C variant.

To further enhance its properties, the biochar underwent acid treatment and magnetization. Treatment with 5M H₂SO₄ significantly increased the BET surface area to 265 m²/g and reduced ash content to 9.96%. Remarkably, the magnetic biochar produced at 800 °C showed an even greater BET surface area, reaching up to 385 m²/g. Magnetic nanoparticles play a crucial role by enhancing active sites, improving electrostatic interactions, and simplifying the recovery process, thus boosting the efficiency and sustainability of dye removal.

The efficacy of the magnetic biochar in removing methylene blue dye was thoroughly investigated under various conditions, including different pH levels, contact times, temperatures, dosages, and concentrations. The results were impressive: the biochar achieved an 85.47% adsorption of MB dye at a dosage of 0.3 g/L, a concentration of 100 ppm, 30 °C, and a 60-minute contact time at pH 7. The maximum adsorption capacity was determined to be 785.34 mg/g, fitting well with the Langmuir isotherm model, which suggests monolayer adsorption of MB onto the biochar surface. Kinetic studies further revealed that the adsorption process is best described by a pseudo-second-order model, with an R² value of 0.994, indicating that chemisorption is the primary mechanism at play.

This research highlights the significant potential of waste areca nut husk as a feedstock for producing highly effective magnetic biochar. The developed material offers a sustainable and efficient solution for removing hazardous methylene blue dye from industrial wastewater, contributing to cleaner water bodies and a healthier environment. The ease of magnetic separation also adds to its practical applicability for large-scale industrial use.


Source: Chistie, S. M., Naik, S. U., Rajendra, P., Apeksha, Mishra, R. K., Albasher, G., Chinnam, S., Jeppu, G. P., Arif, Z., & Hameed, J. (2025). Production and characterization of magnetic Biochar derived from pyrolysis of waste areca nut husk for removal of methylene blue dye from wastewater. Scientific Reports, 15(1), 23209.


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