Ighalo, Abidemi, et al (2024) Retort Co-carbonization of Daniellia oliveri Leaves: Effect of Cow Dung Co-feed on Biochar Properties. Waste and Biomass Valorization. https://doi.org/10.1007/s12649-024-02461-z

In sub-Saharan Africa, Daniellia oliveri trees shed a substantial amount of leaves during the dry season. This study explores the potential of retort carbonization, a novel biomass conversion technique, to produce high-quality biochar (BC) from these leaves. Additionally, it investigates the impact of using cow dung as a co-feed on the quality of the biochar.

The process involved ambient pressure and a 100-minute process time. Biochar yields were analyzed for both Daniellia oliveri leaves (DO-BC) and cow dung co-feed (DC-BC) at different peak temperatures. Characterization techniques including SEM, EDS, FTIR, DTA/TGA, and BET analysis were employed.

The study revealed a higher biochar yield for DC-BC compared to DO-BC. Cow dung co-feed resulted in increased specific surface area and morphological differences in the biochar, with enhanced surface heterogeneity and more inorganic elements observed in DC-BC. Functional group analysis indicated a greater presence of certain groups, such as C–O and C–H, in biochar produced with cow dung co-feed.

The systematic addition of cow dung as a secondary component to the feedstock proved beneficial, improving both the yield and surface properties of the final biochar obtained. This research underscores the potential of utilizing agricultural by-products to enhance biochar production efficiency and quality, offering promising avenues for sustainable biomass utilization in sub-Saharan Africa and beyond.



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