Xiao, et al (2024) Cellulose-based aerogel derived N, B-co-doped porous biochar for high-performance CO2capture and supercapacitor. International Journal of Biological Macromolecules. https://doi.org/10.1016/j.ijbiomac.2024.132078

A recent study published in the International Journal of Biological Macromolecules unveils a novel N, B-co-doped porous biochar derived from cellulose aerogel, demonstrating significant potential for CO2 capture and supercapacitor applications. The research, led by Jianfei Xiao and colleagues, employs a modified alkali-urea method to synthesize this innovative material, which is activated using potassium citrate.

The study highlights several key advancements:

  1. Efficient Synthesis: Using a modified alkali-urea method, N and B atoms are doped in situ into the cellulose aerogel. Potassium citrate acts both as an activator and a salt template, creating a well-defined nanostructure.
  2. High CO2 Capture: The resulting biochar exhibits a superior CO2 adsorption capacity of 4.19 mmol·g⁻¹ at 298 K and 100 kPa, along with high selectivity and exceptional reusability.
  3. Enhanced Supercapacitor Performance: The N, B-co-doped biochar delivers a high specific capacitance of 220.9 F·g⁻¹ at 1 A·g⁻¹, and the symmetric supercapacitor exhibits an energy density of 9 Wh·kg⁻¹ at a power density of 100 W·kg⁻¹.

The cellulose-based aerogel is derived from linters, a sustainable and cost-effective biomass, making this approach both environmentally friendly and scalable. This study not only introduces a promising bifunctional material for environmental and energy applications but also provides insights into the use of mild organic activators for biochar production.

The research underscores the potential of N, B-co-doped porous biochar in addressing critical challenges in CO2 capture and electrochemical energy storage, offering a pathway to scalable, efficient, and sustainable solutions.


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