Rani, M., Keshu & Shanker, U. Green synthesis of sunlight active rice husk biochar loaded with metal ferrite nanocomposite for efficient removal of pesticides: kinetics and photoactivity. Biomass Conv. Bioref. (2024). https://doi.org/10.1007/s13399-024-06000-7


The improper disposal and persistent nature of pesticides like Lindane and DDE have raised serious health concerns due to their endocrine-disrupting and genotoxic effects. A promising solution is photocatalysis, using nanomaterials to break down these toxic chemicals in wastewater. Recent research focused on a biochar (BC)-loaded CoFe2O4 nanocomposite (BC@CoFe2O4), derived from agricultural waste like rice husks, for the photocatalytic degradation of Endosulfan and 4,4-DDD pesticides. This semi-crystalline composite demonstrated excellent removal rates—95% for Lindane and 91% for DDE—under optimal conditions. The degradation followed Langmuir adsorption and first-order kinetics, with hydroxyl radicals playing a key role. Notably, BC@CoFe2O4 proved highly sustainable, retaining its effectiveness over six cycles with minimal decline. Given its cost-effectiveness, eco-friendliness, and impressive surface properties, this nanocomposite offers significant potential for industrial applications in environmental cleanup.


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